000 | 02670namaa2200409uu 4500 | ||
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001 | oapen49335 | ||
003 | oapen | ||
005 | 20231220171420.0 | ||
006 | m o d | ||
007 | cr|mn|---annan | ||
008 | 210602s2019 xx |||||o ||| 0|eng d | ||
020 | _aintechopen.81332 | ||
024 | 7 |
_a10.5772/intechopen.81332 _2doi |
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040 |
_aoapen _coapen |
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041 | 0 | _aeng | |
042 | _adc | ||
072 | 7 |
_aPNRS _2bicssc |
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100 | 1 |
_aLeiza, Jose R. _4auth _91584693 |
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245 | 1 | 0 | _aChapter Waterborne Acrylic/CeO2 Nanocomposites for UV Blocking Clear Coats |
260 |
_bInTechOpen _c2019 |
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300 | _a1 online resource | ||
336 |
_atext _btxt _2rdacontent |
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337 |
_acomputer _bc _2rdamedia |
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338 |
_aonline resource _bcr _2rdacarrier |
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506 | 0 |
_aOpen Access _fUnrestricted online access _2star |
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520 | _aThe encapsulation of inorganic nanoparticles into polymer particles opens the door to countless applications taking advantage of the properties of both phases. In this chapter the UV absorbing capacity of CeO2 nanoparticles and the film forming capacity of acrylic polymers are combined. A synthetic route to produce waterborne acrylic/CeO2 hybrid nanocomposites for UV absorbing coatings applications is presented. This strategy leads to encapsulated morphology of the CeO2 nanoparticles into the polymer particles and therefore to the lack of agglomeration during film formation. A mathematical model developed for inorganic/organic hybrid systems is able to explain the morphology evolution from the initial monomer droplet to the polymer particles. The films cast from these latexes are transparent and show excellent UV absorption that increases with the amount of cerium oxide nanoparticles in the hybrid latex. Finally, the photoactivity behavior that the CeO2 nanoparticles may have on the polymeric matrix is studied, discarding additional effects on the acrylic polymer matrix. | ||
540 |
_aCreative Commons _fhttps://creativecommons.org/licenses/by/3.0/ _2cc _uhttps://creativecommons.org/licenses/by/3.0/ |
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546 | _aEnglish | ||
650 | 7 |
_aSolid state chemistry _2bicssc _9153680 |
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653 | _awaterborne polymer dispersions, CeO2 nanoparticles, hybrid nanocomposites, encapsulation, UV absorption | ||
700 | 1 |
_aAguirre, Miren _4auth _91584694 |
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700 | 1 |
_aPaulis, Maria _4auth _91584695 |
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773 | 1 | _7nnaa | |
793 | 0 | _aOAPEN Library. | |
856 | 4 | 0 |
_uhttps://library.oapen.org/bitstream/id/d9e07b78-4d4d-4f2b-bbec-66b938f3856f/63807.pdf _70 _zOpen Access: OAPEN Library, download the publication |
856 | 4 | 0 |
_uhttps://library.oapen.org/handle/20.500.12657/49335 _70 _zOpen Access: OAPEN Library: description of the publication |
999 |
_c3070874 _d3070874 |