000 02670namaa2200409uu 4500
001 oapen49335
003 oapen
005 20231220171420.0
006 m o d
007 cr|mn|---annan
008 210602s2019 xx |||||o ||| 0|eng d
020 _aintechopen.81332
024 7 _a10.5772/intechopen.81332
_2doi
040 _aoapen
_coapen
041 0 _aeng
042 _adc
072 7 _aPNRS
_2bicssc
100 1 _aLeiza, Jose R.
_4auth
_91584693
245 1 0 _aChapter Waterborne Acrylic/CeO2 Nanocomposites for UV Blocking Clear Coats
260 _bInTechOpen
_c2019
300 _a1 online resource
336 _atext
_btxt
_2rdacontent
337 _acomputer
_bc
_2rdamedia
338 _aonline resource
_bcr
_2rdacarrier
506 0 _aOpen Access
_fUnrestricted online access
_2star
520 _aThe encapsulation of inorganic nanoparticles into polymer particles opens the door to countless applications taking advantage of the properties of both phases. In this chapter the UV absorbing capacity of CeO2 nanoparticles and the film forming capacity of acrylic polymers are combined. A synthetic route to produce waterborne acrylic/CeO2 hybrid nanocomposites for UV absorbing coatings applications is presented. This strategy leads to encapsulated morphology of the CeO2 nanoparticles into the polymer particles and therefore to the lack of agglomeration during film formation. A mathematical model developed for inorganic/organic hybrid systems is able to explain the morphology evolution from the initial monomer droplet to the polymer particles. The films cast from these latexes are transparent and show excellent UV absorption that increases with the amount of cerium oxide nanoparticles in the hybrid latex. Finally, the photoactivity behavior that the CeO2 nanoparticles may have on the polymeric matrix is studied, discarding additional effects on the acrylic polymer matrix.
540 _aCreative Commons
_fhttps://creativecommons.org/licenses/by/3.0/
_2cc
_uhttps://creativecommons.org/licenses/by/3.0/
546 _aEnglish
650 7 _aSolid state chemistry
_2bicssc
_9153680
653 _awaterborne polymer dispersions, CeO2 nanoparticles, hybrid nanocomposites, encapsulation, UV absorption
700 1 _aAguirre, Miren
_4auth
_91584694
700 1 _aPaulis, Maria
_4auth
_91584695
773 1 _7nnaa
793 0 _aOAPEN Library.
856 4 0 _uhttps://library.oapen.org/bitstream/id/d9e07b78-4d4d-4f2b-bbec-66b938f3856f/63807.pdf
_70
_zOpen Access: OAPEN Library, download the publication
856 4 0 _uhttps://library.oapen.org/handle/20.500.12657/49335
_70
_zOpen Access: OAPEN Library: description of the publication
999 _c3070874
_d3070874