Perchlorates : production, uses, and health effects / Lawrence E. Matthews, editor.

Includes bibliographical references and index.

Print version record.

PERCHLORATES: PRODUCTION, USES AND HEALTH EFFECTS ; PERCHLORATES: PRODUCTION, USES AND HEALTH EFFECTS ; CONTENTS ; PREFACE ; TRENDS IN THE STUDY OF THE ELECTROCHEMICAL STABILITY OF PERCHLORATE IONS AGAINST REDUCTIVE ATTACKS ; ABSTRACT ; 1. INTRODUCTION ; 2. HETEROGENEOUS CATALYTIC/ELECTROCATALYTIC ASPECTS OF PERCHLORATE REDUCTION ; 3. REACTION MECHANISMS AND ELECTRODE IMPEDANCE ; 4. REDUCTION OF PERCHLORATE IONS IN THE COURSE OF ANODIC DISSOLUTION AND CORROSION OF METALS ; 5. INTERACTION OF PERCHLORATE IONS WITH IRON GROUP METALS IN AQUEOUS MEDIA.

6. INVESTIGATION OF ANION ADSORPTION IN THE COURSE OF COUPLED METAL DISSOLUTION AND PERCHLORATE REDUCTION 7. SOME INTERESTING RESULTS OF PRACTICAL ASPECTS ; CONCLUSIONS ; ACKNOWLEDGMENT ; REFERENCES ; LITHIUM AND MAGNESIUM PERCHLORATE SOLUTIONS AND THEIR INFLUENCE ON THE RATE AND EQUILIBRIUM OF SOME CYCLOADDITION REACTIONS ; ABSRACT ; INTRODUCTION ; ACCELERATION THE DIELS-ALDER REACTION BY COMMON LEWIS ACIDS ; SALT-SOLUTION EFFECT ON THE DIELS-ALDER REACTION ; REACTION (3+2)-CYCLOADDITION; REACTION (2+2)-CYCLOADDITION; CAUSE AND EFFECT ; REFERENCES.

STRUCTURAL AND VIBRATIONAL PROPERTIES OF CHROMYL PERCHLORATEABSTRACT ; INTRODUCTION ; STRUCTURE AND PROPERTIES OF CHROMYL PERCHLORATE ; Structural Analysis ; Vibrational Analysis ; MONODENTATE COORDINATION OF THE PERCHLORATE GROUPS; C2(1) and C2(2) Structures ; Perchlorate Groups ; Chromyl Group ; BIDENTATE COORDINATION OF THE PERCHLORATE GROUPS ; C2(1) Structure ; Perchlorate Group; Chromyl Group ; Summary ; Force Field ; CONCLUSION ; REFERENCES ; PERCHLORATE FORMATION IN ELECTROCHEMICAL WATER DISINFECTION; ABSTRACT ; 1. INTRODUCTION ; 2. OCCURRENCE OF PERCHLORATE IN ELECTROLYSIS.

3. EXPERIMENTAL DETAILS3.1. Laboratory-Scale and Semi-Technical Cells for Water Electrolysis; Chemicals ; Ion analysis ; 3.2. Technical Cells for Brine Electrolysis ; 3.3. Perchlorate Analysis in Experiments Using Technical Cells ; 4. RESULTS AND DISCUSSION; 4.1. Experiments in Laboratory-Scale and Semi-Industrial Cells ; 4.1.1. Polarization ; 4.1.2. Species generation and influence factors ; 4.2. By-Product Formation in Technical Cells Equipped with MO Electrodes ; 5. DISCUSSION OF PROBABLE MECHANISMS ; 5.1. General Consideration ; 5.1. Possible Mechanisms ; CONCLUSIONS ; ACKNOWLEDGMENT.

Symbols and Abbreviations REFERENCES; METAL PERCHLORATES AS LEWIS ACIDS: A POWERFUL AND VERSATILE TOOL IN ORGANIC SYNTHESIS ; ABSTRACT ; INTRODUCTION ; Lithium Perchlorate ; MAGNESIUM PERCHLORATE; ZINC PERCHLORATE ; CONCLUSION ; REFERENCES; ADVANCES IN THE BIOREMEDIATION OF PERCHLORATE; PERCHLORATE RESPIRING BACTERIA ; Ubiquity and Diversity of (Per) Chlorate Reducing Bacteria ; Perchlorate Reducing Isolates ; Electron Donors and Acceptors Used by PRB for Growth ; Nutritional Requirements for PRB ; THE PERCHLORATE DEGRADATION PATHWAY; Effects of NO3- on ClO4- Removal.

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