Palladium in Heterocyclic Chemistry : a Guide for the Synthetic Chemist.

Cover; Handbook of Heter ocylic Chemistry; Copyright; Part 1 Preliminaries; 1.1 Foreword; 1.2 Detailed Contents; 1.3 Notes on the Arrangement of the Material in the Handbook; 1.4 Explanation of the Reference System; Part 2 Structure of Heterocycles; 2.1 Overview; 2.2 Structure of Six-membered Rings; 2.3 Structure of Five-Membered Rings with One Heteroatom; 2.4 Structure of Five-membered Rings with Two or More Heteroatoms; 2.5 Structure of Small and Large Rings; Part 3 Reactivity of Heterocycles; 3.1 Overview; 3.2 Reactivity of Six-membered Rings.

3.3 Reactivity of Five-Membered Rings with One Heteroatom3.4 Reactivity of Five-membered Rings with Two or More Heteroatoms; 3.5 Reactivity of Small and Large Rings; 4 Synthesis of Heterocycles; 4.1 Overview; 4.2 Synthesis of Monocyclic Rings with One Heteroatom; 4.3 Synthesis of Monocyclic Rings with Two or More Heteroatoms; 4.4 Synthesis of Bicyclic Ring Systems Without Ring Junction Heteroatoms; 4.5 Synthesis of Tri- and Polycyclic Ring Systems Without Ring Junction Heteroatoms; 4.6 Synthesis of Fused Ring Systems with Ring Junction Heteroatoms.

4.6.1 Formation of Three- or Four-Membered Rings with One N Atom at a Ring Junction4.6.2 Formation of a Five-Membered Ring with One N Atom at a Ring Junction; 4.6.3 Formation of a Six-Membered Ring with One N Atom at a Ring Junction; 4.6.4 Formation of a Seven-Membered Ring with One N Atom at a Ring Junction; 4.6.5 Two Nitrogen Atoms at a Ring Junction; 4.6.6 Sulfur at a Ring Junction; References; Index; Journal Abbreviations.

Palladium chemistry, despite its immaturity, has rapidly become an indispensable tool for synthetic organic chemists. Heterocycles are of paramount importance in the pharmaceutical industry and palladium chemistry is one of the most novel and efficient ways of making heterocycles. Today, palladium-catalyzed coupling is the method of choice for the synthesis of a wide range of biaryls and heterobiaryls. The number of applications of palladium chemistry to the syntheses of heterocycles has grown exponentially. These developments highlight the need for a monograph dedicated solely to the palla.

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