Solid state electrochemistry / Thomas G. Willard, editor.

Includes bibliographical references and index.

Print version record.

SOLID STATE ELECTROCHEMISTRY; SOLID STATE ELECTROCHEMISTRY ; CONTENTS ; PREFACE ; ELECTROCHEMICAL FORMATION OF PASSIVATING LAYERS AND SURFACE CONDITION DURING ANODIC OXIDATION AND CORROSION OF METALS ; ABSTRACT; INTRODUCTION; 1. CORROSION AND ELECTROCHEMICAL OXIDATION OF SILVER, COPPER AND THEIR ALLOYS IN CONCENTRATED AQUEOUS SOLUTIONS OF ELECTROLYTES ; 1.1. Silver -- a Concentrated Aqueous Solution of Electrolytes ; 1.1.1. Ag -- H2SO4 System ; 1.1.2. Regularities of Film-Formation during Anodic Oxidation of Silver in Thiosulfate Solutions; 1.2. Cu -- H2SO4 System.

1.3. Anodic Oxidation of Silver and Copper Alloys in Concentrated Sulfuric Acid Solutions 1.3.1. Silver -- Copper Alloys; 1.3.2. Silver -- Palladium Alloy ; 2. KINETICS OF PHASE PASSIVATING LAYERS FORMATION ON METALS IN THE CONDITIONS OF OHMIC CONTROL. EFFECT OF INSTABILITY OF THE ELECTRODE REACTION PRODUCTS ; 2.1. Modification of a Layer-Pore Resistance Model for Instability of Electrode Reaction Products ; 2.2. The Experimental Testing of MLPRM; 2.3. Experimental Testing MLPRM; 2.4. Experimental Testing MLPRM.

2.5. Phenomenological Theory of Three-Dimensional Growth of Porous Passivating Layers on Metals 3. FRACTAL GEOMETRY APPROACH AS A CONVENIENT TOOL FOR AN ESTIMATION OF GEOMETRICAL AND ENERGY HETEROGENEITY OF A METAL SURFACE ; 3.1. The Change of Silver Surface Morphology Corroding in Sulfuric Acid Solutions. Effect of Concentration and Temperature ; 3.2. Fractal Properties of Silver Surface after Electrochemical and Chemical Processing in Sulphurous Media ; 3.3. Fractal Properties of Tungsten after Electrochemical Processing in Water-Organic Solutions.

3.4. Fractal Nature of a Metal Surface Energy HeterogeneityCONCLUSION ; REFERENCES; SOLID-STATE AND INTERFACIAL REACTIONS DURING TRANSPASSIVE DISSOLUTION OF STAINLESS ALLOYS ; ABSTRACT ; ABBREVIATIONS ; INTRODUCTION ; A MODEL FOR THE TRANSPASSIVE STATE ; The Passive-to-Transpassive Transition ; Ionic Conduction and Solid-State Growth ; Transpassive Dissolution ; COMPARISON WITH EXPERIMENTAL DATA ; Materials and Electrolytes ; Pure Cr ; Pure Mo; Pure Ni ; Ferritic Steels ; Austenitic Steels ; NICKEL BASED ALLOYS ; Model Alloys; Industrial Alloys ; SUMMARY AND CONCLUSIONS ; REFERENCES.

ELECTROCHEMICAL BEHAVIOUR OF HETEROCYCLIC FUNGICIDES AND HERBICIDES ABSTRACT; INTRODUCTION; EXPERIMENTAL ; RESULTS AND DISCUSSION ; 2-Mercaptopyridine-N-Oxide (Pyrithione) ; Triazine Herbicides ; Parent Compounds ; Chlorinated Triazines; Methylthio Herbicides ; Imidazolinone Herbicides ; Pyridine Herbicides ; Model Compounds; Pyridine Herbicides ; ACKNOWLEDGMENTS ; REFERENCES; ELECTRODE PROCESSES ON METALLIC ELECTRODES IN CONTACT WITH FLUORITE-LIKE FCC SOLID ELECTROLYTES ; ABSTRACT ; INTRODUCTION ; POROUS ELECTRODES ; DENSE ELECTRODES.

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