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Advances in materials science research. Volume 25 / Maryann C. Wythers, editor.

Contributor(s): Material type: TextTextSeries: Advances in materials science researchPublication details: New York : Nova Science Publishers, Inc., 2016.Description: 1 online resource (229 pages)Content type:
  • text
Media type:
  • computer
Carrier type:
  • online resource
ISBN:
  • 9781634856195
  • 1634856198
Subject(s): Genre/Form: Additional physical formats: Print version:: Advances in Materials Science Research. Volume 25.DDC classification:
  • 620.11 23
LOC classification:
  • TA404.2
Online resources:
Contents:
ADVANCES IN MATERIALS SCIENCE RESEARCH VOLUME 25 ; ADVANCES IN MATERIALS SCIENCE RESEARCH VOLUME 25 ; CONTENTS ; PREFACE ; Chapter 1 METAKAOLIN AS RAW MATERIAL TO CATALYSTS: AN OVERVIEW ; ABSTRACT ; 1. CATALYSTS ; 2. CLAYS ; 3. KAOLINITE; 4. PRODUCTION OF CATALYSTS FROM METAKAOLIN; REFERENCES ; Chapter 2 SUPRAMOLECULAR ADHESIVE COMPLEXES OF STIMULI-RESPONSIVE POLYMERS ; ABSTRACT; 1. INTRODUCTION: PHENOMENON OF LOWER CRITICAL SOLUTION TEMPERATURE AND ADHESION OF AMPHIPHILIC POLYMERS ; 1.1. Molecular Factors Governing Pressure -- Sensitive Adhesion.
1.2. Molecular Design of Pressure -- Sensitive Adhesives1.3. "Smart" Amphiphilic Hydrogen-Bonding Polymers with Lower Critical Solution Temperature ; 1.3.1. Short Review of Molecular and Thermodynamic Factors Underlying the Lower Critical Solution Temperature ; 1.3.2. LCST Transition as a Collective Property of Amphiphilic Macromolecules and Surrounding Water Molecules ; 1.3.3. Cooperativity of the LCST Transitions ; 1.3.4. LCST of Amphiphilic Polymers in Mixed Solvents; 1.3.5. LCST Behavior of Supramolecular Structures Involving Associative Telechelic Macromolecules.
1.3.6. Peculiarities of LCST-Type Phase Separation in Aqueous Solutions of Polymers Employed in Present Research1.3.6.1. Poly(N-vinyl Pyrrolidone and Poly(N-vinyl Caprolactam) ; 1.3.6.2. Poly(N-Isopropyl Acrylamide) ; 1.3.6.3. Comparison of Poly(N-vinyl Caprolactam) and Poly(N-Isopropyl Acrylamide) Properties; 1.3.6.4. Poly(Ethylene Glycol) -- 400 ; 1.4. Structure and Properties of a Model Pressure-Sensitive Adhesive Based on H-bonded complex of Poly(N-Vinyl Pyrrolidone) with Short-Chain Poly(Ethylene Glycol) ; 1.5. Adhesion of Thermoresponsive Polymers ; 2. MATERIALS AND METHODS.
2.1. Materials 2.2. Preparation of Samples ; 2.3. Cloud Point Determination ; 2.4. Water Vapor Absorption Isotherms ; 2.5. Peel Adhesion Testing ; 2.6. Probe Tack Adhesion ; 2.7. Linear Viscoelastic Properties; 2.8. Thermogravimetric Analysis (TGA) ; 2.9. Differential Scanning Calorimetry; 2.10. Microcalorimetric Measurements ; 2.11. The X-Ray Diffraction Patterns ; 2.12. Contact Angle Measurements ; 2.13. Quantum Chemical Calculations ; 3. EVALUATION OF ENERGY AND MECHANISM OF HYDROGEN BONDING IN POLYMER -- PEG -- WATER SYSTEM ; 3.1. H-bonded PVP -- PEG Complex Formation.
3.2. Hydrogen Bonding in PVCL -- PEG System 3.3. Mechanism and Energy of Hydrogen Bonding between Terminal Telechelic PEG Hydroxyl Groups and Complementary PNIPAM Functional Groups ; 4. PHASE BEHAVIOR OF PVCL -- PEG AND PNIPAM -- PEG BLENDS; 4.1. Thermogravimetric Analysis of Initial Polymers and Their Blends with PEG-400 ; 4.2. Phase Behavior of Initial Polymers ; 4.3. Phase Behavior of PVCL -- PEG Blends ; 4.4. Phase Behavior of PNIPAM -- PEG Blends ; 4.5. X-Ray Diffraction Study of PNIPAM and PNIPAM -- PEG Blends.
5. FROM PHASE BEHAVIOR TO STOICHIOMETRY AND MOLECULAR STRUCTURE OF PVP -- PEG, PVCL -- PEG AND PNIPAM -- PEG BLENDS.
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Includes index.

Print version record.

ADVANCES IN MATERIALS SCIENCE RESEARCH VOLUME 25 ; ADVANCES IN MATERIALS SCIENCE RESEARCH VOLUME 25 ; CONTENTS ; PREFACE ; Chapter 1 METAKAOLIN AS RAW MATERIAL TO CATALYSTS: AN OVERVIEW ; ABSTRACT ; 1. CATALYSTS ; 2. CLAYS ; 3. KAOLINITE; 4. PRODUCTION OF CATALYSTS FROM METAKAOLIN; REFERENCES ; Chapter 2 SUPRAMOLECULAR ADHESIVE COMPLEXES OF STIMULI-RESPONSIVE POLYMERS ; ABSTRACT; 1. INTRODUCTION: PHENOMENON OF LOWER CRITICAL SOLUTION TEMPERATURE AND ADHESION OF AMPHIPHILIC POLYMERS ; 1.1. Molecular Factors Governing Pressure -- Sensitive Adhesion.

1.2. Molecular Design of Pressure -- Sensitive Adhesives1.3. "Smart" Amphiphilic Hydrogen-Bonding Polymers with Lower Critical Solution Temperature ; 1.3.1. Short Review of Molecular and Thermodynamic Factors Underlying the Lower Critical Solution Temperature ; 1.3.2. LCST Transition as a Collective Property of Amphiphilic Macromolecules and Surrounding Water Molecules ; 1.3.3. Cooperativity of the LCST Transitions ; 1.3.4. LCST of Amphiphilic Polymers in Mixed Solvents; 1.3.5. LCST Behavior of Supramolecular Structures Involving Associative Telechelic Macromolecules.

1.3.6. Peculiarities of LCST-Type Phase Separation in Aqueous Solutions of Polymers Employed in Present Research1.3.6.1. Poly(N-vinyl Pyrrolidone and Poly(N-vinyl Caprolactam) ; 1.3.6.2. Poly(N-Isopropyl Acrylamide) ; 1.3.6.3. Comparison of Poly(N-vinyl Caprolactam) and Poly(N-Isopropyl Acrylamide) Properties; 1.3.6.4. Poly(Ethylene Glycol) -- 400 ; 1.4. Structure and Properties of a Model Pressure-Sensitive Adhesive Based on H-bonded complex of Poly(N-Vinyl Pyrrolidone) with Short-Chain Poly(Ethylene Glycol) ; 1.5. Adhesion of Thermoresponsive Polymers ; 2. MATERIALS AND METHODS.

2.1. Materials 2.2. Preparation of Samples ; 2.3. Cloud Point Determination ; 2.4. Water Vapor Absorption Isotherms ; 2.5. Peel Adhesion Testing ; 2.6. Probe Tack Adhesion ; 2.7. Linear Viscoelastic Properties; 2.8. Thermogravimetric Analysis (TGA) ; 2.9. Differential Scanning Calorimetry; 2.10. Microcalorimetric Measurements ; 2.11. The X-Ray Diffraction Patterns ; 2.12. Contact Angle Measurements ; 2.13. Quantum Chemical Calculations ; 3. EVALUATION OF ENERGY AND MECHANISM OF HYDROGEN BONDING IN POLYMER -- PEG -- WATER SYSTEM ; 3.1. H-bonded PVP -- PEG Complex Formation.

3.2. Hydrogen Bonding in PVCL -- PEG System 3.3. Mechanism and Energy of Hydrogen Bonding between Terminal Telechelic PEG Hydroxyl Groups and Complementary PNIPAM Functional Groups ; 4. PHASE BEHAVIOR OF PVCL -- PEG AND PNIPAM -- PEG BLENDS; 4.1. Thermogravimetric Analysis of Initial Polymers and Their Blends with PEG-400 ; 4.2. Phase Behavior of Initial Polymers ; 4.3. Phase Behavior of PVCL -- PEG Blends ; 4.4. Phase Behavior of PNIPAM -- PEG Blends ; 4.5. X-Ray Diffraction Study of PNIPAM and PNIPAM -- PEG Blends.

5. FROM PHASE BEHAVIOR TO STOICHIOMETRY AND MOLECULAR STRUCTURE OF PVP -- PEG, PVCL -- PEG AND PNIPAM -- PEG BLENDS.

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