MARC details
| 000 -LEADER |
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| fixed length control field |
02744naaaa2200265uu 4500 |
| 001 - CONTROL NUMBER |
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| control field |
https://directory.doabooks.org/handle/20.500.12854/57601 |
| 005 - DATE AND TIME OF LATEST TRANSACTION |
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| control field |
20220714154201.0 |
| 020 ## - INTERNATIONAL STANDARD BOOK NUMBER |
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| International Standard Book Number |
KSP/3662003 |
| 020 ## - INTERNATIONAL STANDARD BOOK NUMBER |
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| International Standard Book Number |
3937300031 |
| 024 7# - OTHER STANDARD IDENTIFIER |
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| Standard number or code |
10.5445/KSP/3662003 |
| Terms of availability |
doi |
| 041 0# - LANGUAGE CODE |
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| Language code of text/sound track or separate title |
English |
| 042 ## - AUTHENTICATION CODE |
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| Authentication code |
dc |
| 100 1# - MAIN ENTRY--PERSONAL NAME |
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| Personal name |
Rodriguez Betancourtt, V.M. |
| Relator code |
auth |
| 9 (RLIN) |
1563959 |
| 245 10 - TITLE STATEMENT |
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| Title |
Raman spectroscopic study of high temperature rare earth metal - rare earth halide solutions: Ln-LnX3- and LnX2-LnX3-(LiX-KX)eu systems (Ln: Nd, Ce; X: Cl, I) [online] |
| 260 ## - PUBLICATION, DISTRIBUTION, ETC. (IMPRINT) |
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| Name of publisher, distributor, etc |
KIT Scientific Publishing |
| Date of publication, distribution, etc |
2003 |
| 506 0# - RESTRICTIONS ON ACCESS NOTE |
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| Terms governing access |
Open Access |
| Source of term |
star |
| Standardized terminology for access restriction |
Unrestricted online access |
| 520 ## - SUMMARY, ETC. |
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| Summary, etc |
In this work new Raman spectroscopic experiments on rare earth metal-rare earth trihalide melts (Ln-LnX3 and LnX2-LnX3: Ln=Ce, Nd; X=Cl, I) and their mixtures in alkali halide eutectic solvents ((LiX-KX)eu; X=Cl, I) are presented. The main results can be summarized as follows:- The Raman spectra of following trihalide systems have been measured for the first time: CeCl3, CeI3, NdI3 and their mixtures in the respective alkali halide eutectic solvent. The structure of the LnX3 in the solvent can be characterized by octahedral complexes. The force constants decrease from the chlorides to the iodides. - The Raman spectra of the following dihalides have been observed in this work: NdCl2, CeI2 and their mixtures in the alkali halide solvent. Interestingly, CeCl2 might form as intermediate species on doping CeCl3 with Ce. It is not a stable compound in the Ce-CeCl3 phase diagram.- With respect to the above mentioned main objective the following conclusions can be drawn: (i) On mixing of NdCl2 with NdCl3 in (LiCl-KCl)eu the undisturbed spectra of both components can be observed simultaneously. This is in agreement with the suggested intervalence charge transfer hopping mechanism if one assumes a hopping rate below 1012.(ii) Even though CeCl2 might form as intermediate, in the equilibrium spectra of liquid Ce-CeCl3-(LiCl-KCl)eu only the typical - 36 CeCl -octahedra can be identified. This supports the assumption that in these systems the electronic defect states are probably mobile Drude-like electrons which do not lead to new Raman detectable species. A qualitatively similar observation was made for CeI2-CeI3-(LiI-KI)eu melts. |
| 540 ## - TERMS GOVERNING USE AND REPRODUCTION NOTE |
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| Terms governing use and reproduction |
All rights reserved |
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http://oapen.org/content/about-rights |
| 546 ## - LANGUAGE NOTE |
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| Language note |
English |
| 653 ## - INDEX TERM--UNCONTROLLED |
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| Uncontrolled term |
Seltenerdhalogenide |
| 653 ## - INDEX TERM--UNCONTROLLED |
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| Uncontrolled term |
Hochtemperatur |
| 653 ## - INDEX TERM--UNCONTROLLED |
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| Uncontrolled term |
Raman-Spektroskopie |
| 856 40 - ELECTRONIC LOCATION AND ACCESS |
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| Host name |
www.oapen.org |
| Uniform Resource Identifier |
<a href="https://www.ksp.kit.edu/3937300031">https://www.ksp.kit.edu/3937300031</a> |
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0 |
| Public note |
DOAB: download the publication |
| 856 40 - ELECTRONIC LOCATION AND ACCESS |
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| Host name |
www.oapen.org |
| Uniform Resource Identifier |
<a href="https://directory.doabooks.org/handle/20.500.12854/57601">https://directory.doabooks.org/handle/20.500.12854/57601</a> |
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0 |
| Public note |
DOAB: description of the publication |
