Calixarene Complexes: Synthesis, Properties and Applications

Berberan-Santos, Mario

Calixarene Complexes: Synthesis, Properties and Applications - Basel, Switzerland MDPI - Multidisciplinary Digital Publishing Institute 2021 - 1 electronic resource (198 p.)

Open Access

A growing interest has been devoted to the development of host systems for ionic and neutral species based on calixarenes. These cyclic oligomers show important host-guest properties, which has led to numerous applications in a broad range of fields, including organocatalysis, sensing, extraction and separation, and, more recently, biomedical applications. The relative ease of the functionalization of their upper and lower rims and the presence of a pre-organized cavity that is available in different sizes and conformations make calixarenes attractive building blocks for the construction of supramolecular assemblies. This book presents the most recent developments on the host-guest properties of calixarenes, as well as the new synthetic methods and applications.


Creative Commons


English

books978-3-0365-1634-9 9783036516332 9783036516349

10.3390/books978-3-0365-1634-9 doi


Research & information: general

thiosemicarbazone calix[4]arene metal complex X-ray structure antimicrobial anticancer copper supramolecular inclusion complex fluorescence sensor density functional theory calix[3]arenes metacyclophanes calixarene-analogous metacyclophanes inherent chirality host-guest chemistry dihomooxacalix[4]arenes naphthyl(thio)urea anion receptors alkylammonium hydrochlorides ditopic receptors chiral recognition NMR studies UV-Vis absorption studies fluorescence studies X-ray diffraction DFT calculations calixarene resorcinarene pillararene antibiotic fungicide biofilm inhibition calixarenes threading chirality barfate salts pseudorotaxane chiral axles chiral wheels. calixarene-like structure polyoxometalates nitronate crystal structure host-guest chemistry anion receptor anion sensors lanthanides UV-vis studies quantum yields lifetime measurements noncovalent synthesis hierarchical control calix[4]tubes metallo-porphyrins phthalimide derivatives conventional synthesis microwave irradiation ball milling NMR spectroscopy electronic absorption and fluorescence studies

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