Carborane: Dedicated to the Work of Professor Alan Welch

Stogniy, Marina Yu.

Carborane: Dedicated to the Work of Professor Alan Welch - Basel MDPI - Multidisciplinary Digital Publishing Institute 2022 - 1 electronic resource (114 p.)

Open Access

This Special Issue on carboranes is dedicated to Prof. Alan Welch on the occasion of his retirement and his outstanding contributions to the field of carborane chemistry. Polyhedral carboranes lie at the interface of organic and inorganic chemistry. One of their most attractive and important features is the variety and beauty of their chemical structures. They have found applications as diverse as catalysis, in Boron Neutron Capture Therapy, as liquid crystals and as semiconductors. This Special Issue illustrates the very comprehensive world of heteroborane chemistry, from liquid crystals to BNCT agents, di-halogen bonding to quantum chemical calculations of tetrel complexes of the carbonium ylide CB11H11, nickellacarboranes as potential acid-base sensors to revealing how the selective formations of metallacarborane diastereomers can arise and metallacarboranes as function as radical cation salts with dielectric or semiconductor properties.


Creative Commons


English

books978-3-0365-3620-0 9783036536194 9783036536200

10.3390/books978-3-0365-3620-0 doi


Research & information: general

carboranes DFT reaction pathways boron chemistry o-carborane sulfa-Michael addition reaction cysteine boron neutron capture therapy o-carborane decapitation labeled compound 1,1'-bis(o-carborane) deboronation metalation bis(nickelation) diastereoisomers stereospecific boron clusters liquid crystals fluorescence cholesterol nido-carborane nitrilium derivatives nickel(II) half-sandwich complexes synthesis structure Lewis acid carborane carbonium ylide tetrel bond quantum chemistry electron density ELF iodo derivatives dihalogen bond X-ray structure quantum chemical calculations iron bis(1,2-dicarbollide) chromium bis(1,2-dicarbollide) tetramethyltetrathiafulvalene tetramethyltetraselenafulvalene radical-cation salts crystal and molecular structure electric conductivity n/a

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