Dzhemilev reaction in organic and organometallic synthesis /

Dʹi︠a︡konov, Vladimir A.

Dzhemilev reaction in organic and organometallic synthesis / Vladimir A. D'yakonov. - 1 online resource. - Chemistry research and applications series . - Chemistry research and applications series. .

Includes bibliographical references (pages 77-89) and index.

Introduction -- History of discovery -- Ethylmagnesiation of olefins catalyzed by Zr complexes -- Catalytic cycloalumination and cyclomagnesiation of olefins, acetylenes, and allenes mediated by Mg or Al alkyls -- Catalytic cycloalumination of olefins and 1,2-dienes to aluminacyclopentanes -- Catalytic cycloalumnation of acetylenes to aluminacyclopentenes and aluminacyclopentadienes -- Cyclomagnesiation of olefins and 1,2-dienes to magnesacyclopentanes affected by Zr- and Ti-catalysts -- Catalytic cyclomagnesiation of acetylenes -- On mechanism of olefin ethylmagnesiation and cycloalumination catalyzed by Zr complexes -- Synthesis of macro metallacarbocycles through the catalytic cyclometalation reaction of unsaturated compounds.

9781617616594 epub 1617616591 softcover softcover

2019720549


Organometallic compounds--Synthesis.
Transition metals.
Phase-transfer catalysis.
Composés organométalliques--Synthèse.
Métaux de transition.
Catalyse par transfert de phase.
SCIENCE--Chemistry--Organic.
Organometallic compounds--Synthesis.
Phase-transfer catalysis.
Transition metals.


Electronic books.
Electronic books.

QD411.7.S94

547.2

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